| Doubles | |
|---|---|
| 2010 Barcelona Open Banco Sabadell | |
| Champions |
|
| Runners-up |
|
| Final score | 4–6, 6–3, [10-5] |
Daniel Nestor and Nenad Zimonjić defend their 2009 title. They defeated Lleyton Hewitt and Mark Knowles in the final (4–6, 6–3, [10-5]).
All seeds receive a bye into the second round.