| Women's Singles | |
|---|---|
| 2012 Rogers Cup | |
| Champion |
|
| Runner-up |
|
| Final score | 7–5, 2–6, 6–3 |
Serena Williams was the defending champion, but chose not to compete this year.
Petra Kvitová defeated Li Na for the championship, 7–5, 2–6, 6–3.
All seeds receive a bye into the second round.