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Aluminium(III) selenide

Aluminium selenide
Aluminum selenide
Names
Other names
Aluminium(III) selenide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.013.737
EC Number 215-110-6
PubChem CID
Properties
Al2Se3
Molar mass 290.84 g/mol
Appearance yellow to brown powder
Odor odorless
Density 3.437 g/cm3
Melting point 947 °C (1,737 °F; 1,220 K)
decomposes
Structure
Monoclinic, mS20, Space group Cc, No. 9
Thermochemistry
154.8 J/mol K
-566.9 kJ/mol
Hazards
not listed
NFPA 704
Flammability code 0: Will not burn. E.g., water Health code 3: Short exposure could cause serious temporary or residual injury. E.g., chlorine gas Reactivity code 3: Capable of detonation or explosive decomposition but requires a strong initiating source, must be heated under confinement before initiation, reacts explosively with water, or will detonate if severely shocked. E.g., fluorine Special hazards (white): no codeNFPA 704 four-colored diamond
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
YesY  (what is YesYN ?)
Infobox references

Aluminium selenide is the inorganic compound with the formula Al2Se3.

It is a solid prepared by igniting a mixture of the elements at 1,000 °C (1,830 °F):

The pure compound is white, but typical samples are coloured. Samples of aluminium selenide must be protected from moisture, because the compound hydrolyzes readily, giving off highly toxic hydrogen selenide gas:

Al2Se3 has been used as a precursor to hydrogen selenide, which is released when the solid is treated with acids.

Aluminium selenide should be stored and handled away from moisture and air.


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