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Amorphous silica

Silicon dioxide
Sample of silicon dioxide.jpg
Names
IUPAC name
Silicon dioxide
Other names
Quartz

Silica
Silicic oxide
Silicon(IV) oxide

Crystalline silica
Identifiers
ChEBI
ChemSpider
ECHA InfoCard 100.028.678
EC Number 231-545-4
E number E551 (acidity regulators, ...)
200274
KEGG
MeSH Silicon+dioxide
PubChem CID
RTECS number VV7565000
UNII
Properties
SiO2
Molar mass 60.08 g/mol
Appearance Transparent solid (Amorphous) White/Whitish Yellow (Powder/Sand)
Density 2.648 (α-quartz), 2.196 (amorphous) g·cm−3
Melting point 1,713 °C (3,115 °F; 1,986 K) (amorphous) to
Boiling point 2,950 °C (5,340 °F; 3,220 K)
−29.6·10−6 cm3/mol
Thermal conductivity 12 (|| c-axis), 6.8 (⊥ c-axis), 1.4 (am.) W/(m⋅K)
1.544 (o), 1.553 (e)
Hazards
NFPA 704
Flammability code 0: Will not burn. E.g., water Health code 0: Exposure under fire conditions would offer no hazard beyond that of ordinary combustible material. E.g., sodium chloride Reactivity code 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g., liquid nitrogen Special hazards (white): no codeNFPA 704 four-colored diamond
US health exposure limits (NIOSH):
PEL (Permissible)
TWA 20 mppcf (80 mg/m3/%SiO2) (amorphous)
REL (Recommended)
TWA 6 mg/m3 (amorphous)
Ca TWA 0.05 mg/m3
IDLH (Immediate danger)
3000 mg/m3 (amorphous)
Ca [25 mg/m3 (cristobalite, tridymite); 50 mg/m3 (quartz)]
Related compounds
Related diones
Carbon dioxide

Germanium dioxide
Tin dioxide
Lead dioxide

Related compounds
Silicon monoxide

Silicon sulfide

Thermochemistry
42 J·mol−1·K−1
−911 kJ·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N  (what is YesYN ?)
Infobox references

Silica
Silicic oxide
Silicon(IV) oxide

Germanium dioxide
Tin dioxide
Lead dioxide

Silicon sulfide

Silicon dioxide, also known as silica (from the Latin silex), is an oxide of silicon with the chemical formula SiO2, most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one of the most complex and most abundant families of materials, existing as a compound of several minerals and as synthetic product. Notable examples include fused quartz, fumed silica, silica gel, and aerogels. It is used in structural materials, microelectronics as component in the food and pharmaceutical industry.

Inhaling finely divided crystalline silica is toxic and can lead to silicosis, bronchitis, lung cancer and systemic autoimmune diseases, such as lupus and rheumatoid arthritis.

In the majority of silicates, the Si atom shows tetrahedral coordination, with four oxygen atoms surrounding a central Si atom. The most common example is seen in the quartzite polymorph.


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