General properties | ||||||||||||||||
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Pronunciation |
/ˈbroʊmiːn, |
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Appearance | reddish-brown | |||||||||||||||
Standard atomic weight (Ar, standard) | [, 79.901] conventional: 79.907 79.904 | |||||||||||||||
Bromine in the periodic table | ||||||||||||||||
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Atomic number (Z) | 35 | |||||||||||||||
Group | group 17 (halogens) | |||||||||||||||
Period | period 4 | |||||||||||||||
Element category | reactive nonmetal | |||||||||||||||
Block | p-block | |||||||||||||||
Electron configuration | [Ar] 3d10 4s2 4p5 | |||||||||||||||
Electrons per shell
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2, 8, 18, 7 | |||||||||||||||
Physical properties | ||||||||||||||||
Phase at STP | liquid | |||||||||||||||
Melting point | 265.8 K (−7.2 °C, 19 °F) | |||||||||||||||
Boiling point | 332.0 K (58.8 °C, 137.8 °F) | |||||||||||||||
Density (near r.t.) | Br2, liquid: 3.1028 g/cm3 | |||||||||||||||
Triple point | 265.90 K, 5.8 kPa | |||||||||||||||
Critical point | 588 K, 10.34 MPa | |||||||||||||||
Heat of fusion | (Br2) 10.571 kJ/mol | |||||||||||||||
Heat of vaporisation | (Br2) 29.96 kJ/mol | |||||||||||||||
Molar heat capacity | (Br2) 75.69 J/(mol·K) | |||||||||||||||
Vapour pressure
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Atomic properties | ||||||||||||||||
Oxidation states | 7, 5, 4, 3, 1, −1 |
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Electronegativity | Pauling scale: 2.96 | |||||||||||||||
Ionisation energies |
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Atomic radius | empirical: 120 pm | |||||||||||||||
Covalent radius | 120±3 pm | |||||||||||||||
Van der Waals radius | 185 pm | |||||||||||||||
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Miscellanea | ||||||||||||||||
Crystal structure | orthorhombic | |||||||||||||||
Speed of sound | 206 m/s (at 20 °C) | |||||||||||||||
Thermal conductivity | 0.122 W/(m·K) | |||||||||||||||
Electrical resistivity | 7.8×1010 Ω·m (at 20 °C) | |||||||||||||||
Magnetic ordering | diamagnetic | |||||||||||||||
Magnetic susceptibility | −56.4·10−6 cm3/mol | |||||||||||||||
CAS Number | 7726-95-6 | |||||||||||||||
History | ||||||||||||||||
Discovery and first isolation | Antoine Jérôme Balard and Carl Jacob Löwig (1825) | |||||||||||||||
Main isotopes of bromine | ||||||||||||||||
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Bromine is a chemical element with symbol Br and atomic number 35. It is the third-lightest halogen, and is a fuming red-brown liquid at room temperature that evaporates readily to form a similarly coloured gas. Its properties are thus intermediate between those of chlorine and iodine. Isolated independently by two chemists, Carl Jacob Löwig (in 1825) and Antoine Jérôme Balard (in 1826), its name was derived from the Ancient Greek βρῶμος ("stench"), referencing its sharp and disagreeable smell.
Elemental bromine is very reactive and thus does not occur free in nature, but in colourless soluble crystalline mineral halide salts, analogous to table salt. While it is rather rare in the Earth's crust, the high solubility of the bromide ion (Br−) has caused its accumulation in the oceans. Commercially the element is easily extracted from brine pools, mostly in the United States, Israel and China. The mass of bromine in the oceans is about one three-hundredth that of chlorine.
At high temperatures, organobromine compounds readily dissociate to yield free bromine atoms, a process that stops free radical chemical chain reactions. This effect makes organobromine compounds useful as fire retardants, and more than half the bromine produced worldwide each year is put to this purpose. Unfortunately, the same property causes ultraviolet sunlight to dissociate volatile organobromine compounds in the atmosphere to yield free bromine atoms, causing ozone depletion. As a result, many organobromide compounds—such as the pesticide methyl bromide—are no longer used. Bromine compounds are still used in well drilling fluids, in photographic film, and as an intermediate in the manufacture of organic chemicals.