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Dichlorodifluoroethylene

Dichlorodifluoroethylene
1,1-Dichloro-2,2-difluoroethylene.svg
1,1-Dichloro-2,2-difluoroethylene
Cis-1,2-dichloro-1,2-difluoroethylene.svg
cis-1,2-Dichloro-1,2-difluoroethylene
Trans-1,2-dichloro-1,2-difluoroethylene.svg
trans-1,2-Dichloro-1,2-difluoroethylene
Names
IUPAC names
1,1-Dichloro-2,2-difluoroethene
(Z)-1,2-Dichloro-1,2-difluoroethene
(E)-1,2-Dichloro-1,2-difluoroethene
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.001.090
PubChem CID
Properties
C2Cl2F2
Molar mass 132.92 g·mol−1
-60.0·10−6 cm3/mol
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N  (what is YesYN ?)
Infobox references

A dichlorodifluoroethylene (systematically named dichlorodifluoroethene) is one of three compounds with the chemical formula C
2
Cl
2
F
2
. Dichlorodifluoroethylenes are colourless gases, and are some of the simplest chlorodifluoroalkenes.

The structural isomers are used as intermediates or precursors in the production of other industrial chemicals.

1,1-Dichloro-2,2-difluoroethylene is a low-boiling liquid that is used a refrigerant. It may also be used as a solvent, but has practical limitations as such, because of its low boiling point (commercial listings, 19 °C; lit. 17 °C).

It is regarded as a hazardous chemical for being toxic by inhalation (see MSDS), and a low-boiling liquid, and it causes irritation when it comes into contact with the skin and mucous membranes. Its ASHRAE number is R-1112a, and its CAS number is 79-35-6. Concentrated 1,1-dichloro-2,2-difluoroethylene can be ignited with ease in the laboratory.

The diastereomers were co-isolated first in 1965, by using a combination of fractional melting and fractional distillation. The cis isomer's ASHRAE number is R-1112c, and its CAS number is 311-81-9. Its melting point is −119.6 °C (−183.3 °F). The trans isomer's ASHRAE number is R-1112t, and its CAS number is 381-71-5. Its melting point is −93.3 °C (−135.9 °F). The diastereomers are commercially only available as a mixtures of varying proportions.


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