Hypofluorite
 Gas-phase structure
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| Names | |
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IUPAC name
Hypofluorous acid
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| Other names
Hydrogen hypofluorite
Hydrogen fluorate(-I) Fluoric(-I) acid Hydrogen monofluoroxygenate(0) hydroxyl fluoride |
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| Identifiers | |
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3D model (JSmol)
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PubChem CID
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| Properties | |
| HOF | |
| Molar mass | 36.0057 g mol−1 |
| Appearance | pale yellow liquid above −117 °C white solid below −117 °C |
| Melting point | −117 °C (−179 °F; 156 K) |
| Boiling point | < 0 °C decomposes at 0 °C |
| Structure | |
| Cs | |
| Related compounds | |
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Other cations
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lithium hypofluorite |
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Related compounds
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hypochlorous acid nitroxyl hydrogen cyanide formaldehyde |
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Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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| Infobox references | |
Hypofluorous acid, HOF, is the only known oxoacid of fluorine and the only known oxoacid which the main atom gains electrons from oxygen to create a negative oxidation state. The oxidation state of the oxygen in hypofluorites is 0. It is also the only that can be isolated as a solid. HOF is an intermediate in the oxidation of water by fluorine, which produces hydrogen fluoride, oxygen difluoride, hydrogen peroxide, ozone and oxygen. HOF is explosive at room temperature, forming HF and O2:
It was isolated in the pure form by passing F2 gas over ice at −40 °C, collecting the HOF gas, and condensing it:
The compound has been characterized in the solid phase by X-ray crystallography as a bent molecule with an angle of 101°. The O–F and O–H bond lengths are 144.2 and 96.4 picometres, respectively. The solid framework consists of chains with O–H···O linkages. The structure has also been analyzed in the gas phase, a state in which the H–O–F bond angle is slightly narrower (97.2°).
Hypofluorous acid in acetonitrile (generated in situ by passing gaseous fluorine through "wet" acetonitrile) serves as a highly electrophilic oxygen-transfer agent. Treating phenanthroline with this reagent yielded the previously elusive 1,10-phenanthroline dioxide, more than 50 years after the first unsuccessful attempt.
This molecule is not very symmetric since the atoms are all different. It only has two symmetry operations: identity (E) and a mirror plane that goes through the three atoms. The assigned point group is Cs.
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