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Names | |||
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IUPAC name
Sodium hypochlorite
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Other names
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Identifiers | |||
3D model (JSmol)
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ChEBI | |||
ChemSpider | |||
ECHA InfoCard | 100.028.790 | ||
EC Number | 231-668-3 | ||
KEGG | |||
PubChem CID
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RTECS number | NH3486300 | ||
UNII | |||
UN number | 1791 | ||
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Properties | |||
NaOCl | |||
Molar mass | 74.442 g/mol | ||
Appearance | greenish-yellow solid (pentahydrate) | ||
Odor | chlorine-like and sweetish | ||
Density | 1.11 g/cm3 | ||
Melting point | 18 °C (64 °F; 291 K) pentahydrate | ||
Boiling point | 101 °C (214 °F; 374 K) (decomposes) | ||
29.3 g/100mL (0 °C) | |||
Acidity (pKa) | 7.5185 | ||
Basicity (pKb) | 6.4815 | ||
Thermochemistry | |||
Std enthalpy of
formation (ΔfH |
-347.1 kJ/mol | ||
Pharmacology | |||
D08AX07 (WHO) | |||
Hazards | |||
Safety data sheet |
ICSC 1119 (solution, >10% active chlorine) ICSC 0482 (solution, <10% active chlorine) |
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EU classification (DSD) (outdated)
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Corrosive (C) Dangerous for the environment (N) |
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R-phrases (outdated) | R31, R34, R50 | ||
S-phrases (outdated) | (S1/2), S28, S45, S50, S61 | ||
NFPA 704 | |||
Related compounds | |||
Other anions
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Sodium chloride Sodium chlorite Sodium chlorate Sodium perchlorate |
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Other cations
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Lithium hypochlorite Calcium hypochlorite |
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Related compounds
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Hypochlorous acid | ||
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references | |||
Sodium hypochlorite is a chemical compound with the formula NaClO. It is composed of a sodium cation (Na+
) and a hypochlorite anion (ClO−
); it may also be viewed as the sodium salt of hypochlorous acid. When dissolved in water it is commonly known as bleach or liquid bleach. Sodium hypochlorite is practically and chemically distinct from chlorine. Sodium hypochlorite is frequently used as a disinfectant or a bleaching agent. The mixture of sodium peroxide (Na2O2) and hydrochloric acid, which react to produce sodium hypochlorite is also termed as oxone.
Household bleach is, in general, a solution containing 3–8% sodium hypochlorite, by weight, and 0.01–0.05% sodium hydroxide; the sodium hydroxide is used to slow the decomposition of sodium hypochlorite into sodium chloride and sodium chlorate.
Sodium hypochlorite has destaining properties. Among other applications, it can be used to remove mold stains, dental stains caused by fluorosis, and stains on crockery, especially those caused by the tannins in tea. It has also been used in laundry detergents and as a surface cleaner.
Its bleaching, cleaning, deodorizing and caustic effects are due to oxidation and hydrolysis (saponification). Organic dirt exposed to hypochlorite becomes water-soluble and non-volatile, which reduces its odor and facilitates its removal.